By not work do you mean they only work for one allignment(evil, nuetral, good)?
Or they just do not work.
It could be based on alignment, but what I meant was that certain techs are race-specific: i.e. the Torian techs only work for the Torians, the Thalan techs only work for the Thalans, etc. These races may still offer these for trade, and will accept payment for them, but when you close the trade window, they will not show up in your list. You will need to learn which techs are race-specific, or you will occasionally get 'played'. Some of these will show up in the trade window with an asterisk (*) next to them, but I don't believe at this time that they all do. If anything along these lines has changed in the latest patch(es), please let me know.