No, I'm not talking about these techs, but about techs like the Krynn's "Interstellar Expansion" which grants a +8 PQ ability bonus or Torian's enhanced adaptation, which grants a +5 PQ ability bonus
You're not noticing a difference because it's a percentage increase. So any planets that are under class 20 won't benefit from a +5 PQ bonus and any planets under class 13 won't benefit from a +8 PQ bonus. At least, that's how I remember it working.
And as far as the planets you haven't colonized yet-the bonus is only applied when you come into possession of them.

There was an issue in DL & DA where the PQ bonus didn't work properly in some fashion (I don't remember the specifics, but I believe it was working on planets you colonized, but not those you invaded), however it was resolved for TA, somewhere in between 1.95 and 2.0.