IIRC it's no on both counts.
The starting cash is hard coded. Nothing you change can affect that.
The starting ships, well you can't just start with a scout, not unless you create a custom map, then i think it is possible.
You can make your own ship style and make some cosmetic changes to the ships, but i beleive their function is hard coded as well.
A suggestion you could do though to make the game less funded at the start is make all your techs that you would go after first much dearer. Or even some of the Planetary Improvemnts. Adjusting the cost of techs and PI's is moddable, but of course that cost will be throughout the game, and for the AI too for shared PI's or any AI with the same tree as you.
Perhaps Zyx, or Dsep will come allong and shed some more light on this for you.