Let me second the recommendation for www.gog.com if you are looking for classic adventure games.
This weekend only there is a sale on RealMyst, which is a classic adventure game. Like $5, but Win 7 could be a problem for anything gog sells, see the forums. No combat as such, but you solve a mystery with a dark side. You also view a walkthru on youtube unless your wife has an IQ above 180. I was too stooopid for the Myst series myself.
Much better would be The Longest Journey, praised by many as the greatest Adventure game of all time. Gog sells it for $10. And the adventurer is female too! There is somewhere a forum of fanatical players. By george, I've almost talked myself into it!
http://www.gog.com/en/gamecard/the_longest_journey
http://www.youtube.com/watch?v=ZTt6Tu-4KDk is the trailer for the original game.
http://www.youtube.com/watch?v=4WQL4bWaFbs&NR=1 is the trailer for the successor, Dreamfall.
Actually, you both might get involved in these two games, which would be nice.
Then too, of course, there's always The Sims! (I will go eat a raw Jalepeno to punish myself for saying that.)
I sort of agree with your wife. As the years roll on, I get more and more tired of games where all the time we are either killing people or giving them cancer. I would really sort of prefer a game like "Bob Bunny Has a Good Day."